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Sodium Bromosmate, Na2OsBr6

Sodium Bromosmate, Na2OsBr6.4H2O, may be prepared by the action of dry hydrogen bromide on sodium osmisulphite, 3Na2O.OsO3.4SO2.5H2O, or better by decomposition of the same with aqueous hydrogen bromide, of density 1.45. A deep purple-red solution is obtained from which long, dark brown prisms crystallise out, possessed of a metallic appearance.

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